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Chemical safety is accomplished by first, BEING AWARE OF
THE CHEMICAL HAZARD; second, by HANDLING THE MATERIAL APPROPRIATELY
WITH THE USE OF PPE and third, by KEEPING THE CHEMICAL UNDER
CONTROL THROUGH A VARIETY OF ENGINEERED SAFEGUARDS. Proper
use and function of all safeguards should be clearly understood
when working in the lab.
A. Ventilation
REPORT ALL NON-OPERATIONAL
FUME HOODS IMMEDIATELY
TO BUILDINGS AND GROUNDS
Open doors and windows
provide one means of ventilation
and should always be kept in mind as a source of
ventilation
Regular maintenance and
inspection will help
ensure working
fume hoods
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Chemical characteristics provide the guideline
by which to use a fume hood. All low Threshold Limit
Value (TLV)/Premissible Exposure Limit (PEL) or
high vapor pressure chemicals should be handled
in a hood that provides at least 80-100 linear foot
per minute of air flow. By lowering the fume hood
sash, air flow will be increased.
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Remember that fume hoods are not storage areas
and should be clean and free from obstruction. In
addition, chemicals have specific density characteristics
which determine how they will be vented, so be sure
to review the MSDS or other information sources
prior to beginning work. In cases of power failures
or when fume hoods are not operational, i.e., with
at least 80-100 linear foot draw, no work should
be performed in the lab.
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B. Storage Areas/Access to Chemicals
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Each lab
should establish procedures for chemical storage
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Establish when the labs will be open, locked and
who has the key. Limited and controlled access can
be accomplished by assigning an individual the responsibility.
Faculty members have been assigned specific laboratory
space and are responsible for limiting and controlling
access to their labs.
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The lab should be well ventilated. Do not overload
cabinets. Ocassional inspections should be performed
for signs of leakage or spillage. Original labels
should be checked and resecured with clear tape
if necessary. Remember compatibility is a prime
concern. Suitable storage space or stockroom areas
should be used in order to minimize storage of chemicals
in laboratories.
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C. Eyewashes and Safety Showers
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These pieces of safety equipment are the first
defense for immediate first aid in the event of
a chemical splash accident or clothing fire.
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Keep free from obstruction.Check routinely for
operable valves and in order to remove debris build-up.
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D. Protective Apparel
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DO NOT
WEAR CONTACT LENSES IN THE LABORATORY
WHEN WORKING WITH CHEMICALS
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Goggles provide protection from chemical splashes
and from glassware that may explode, implode or
simply break by accident. Gloves should be made
of a compatible material to the chemicals in use.
This is especially true when working with solvents.
Thin, disposable gloves may be used when a physical
barrier is needed for skin protection. Check the
integrity of the glove prior to use.
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Lab coats are recommended and serve as a minimum
protection from chemical splashes, providing a barrier
and offering time in order to remove the coat. Coats
will also protect street clothes from any accidential
acid spill. If you think a process is potentially
explosive, work behind a safety shield and use only
small quantities of the reactants.
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E. Dust, Fume and Mist Masks
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These masks
are for use only where particulates are a concern
and should be used in accordance with the manufaturers
specifications
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They are typically NIOSH approved and effective
against benign dust.
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Remember they are not 100% efficient and are dependent
upon the concentration of the contaminant.
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F. Vapor Detection
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ODOR is
not the primary method of vapor detection
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Often the odor threshold can be greater than the
TLV. Regular instrumental monitoring of airborne
chemical concentrations is not usually justified
or practical in general undergraduate laboratories.Depending
on a number of factors (the sampling objective,
nature of the contaminant, laboratory conditions
and the equipment available), either the services
of an outside contractor or the purchase of a monitoring
device will be recomended.
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NOTE: There is a combustible gas indicator available
for determining natural gas leaks. In the event
of a suspected natural gas leak, contact the University
Fire Marshall, Mr. Albert Williams at EXT 5777.
or report to University Security. Ventilate and
evacuate the area in the meantime.
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G. Signs and Labels
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Prominent
signs and labels will be posted to include:
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Emergency phone numbers on all telephones (5666).
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Container content labels including waste receptacles
with a minimum of the chemical name and hazard.
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Chemical storage areas should be posted - Areas
for authorized personnel only.
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Location of first aid equipment.
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Warnings where special or unusual hazards exist
like lasers, x-ray equipment, etc.
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General warnings like no smoking, no food storage.
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Person/phone number to contact in the event of
an emergency.
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For further evaluation of laboratories and rooms for NFPA
code compliance, Responder Signs and HAZCOM signs, contact
Mr. Albert Williams at 727-5777.
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